Light is a fascinating reagent for chemistry as it provides energy to drive reactions, but leaves no trace. In visible light photoredox catalysis the initial electron transfer from the excited dye to a substrate yields radical anion or radical intermediates, which dominate the subsequent chemistry. Carbanions, which are the most important nucleophiles in organic chemistry, are typically not available from photocatalysis. The project PHAROS aims to overcome the current limitation of visible light photocatalysis to radical chemistry and extend its use to carbon nucleophiles. To obtain carbanions for organic synthesis using visible light, we propose three specific project tasks:
Datum
|
1. 9. 2017 - 31. 8. 2022 |
Länderkürzel
|
DE |
Name der begünstigten Einrichtung
|
Universität Regensburg |
Projektleitung
|
Fakultät Chemie und Pharmazie |
Verknüpfung
|
www.uni-regensburg.de |
Förderrahmen & Förderprogramm
|
H2020, ERC-ADG - Advanced Grant |
